为什么 NO 作为配体的存在形式为 NO+ 或 NO - 知乎

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NO是一个有奇数个电子的自由基,它有一个电子位于pi反键轨道里。 如果它以电中性的NO分子形式配位,则配位之后的化合物也会有一个单电子,而且这个单电子必定仍然主要位于NO的pi反键轨道里。


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