知乎盐选 | 9.6 稀土离子和其他金属离子的发光
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有些稀土离子的 4f n−1 5d 组态离 4f n 组态很近，甚至互相重叠。 4f n−1 5d 激发态到 4f n 基态的跃迁在可见光谱区出现，4f n−1 接近半满或全空的稀土离子 4f n−1 5d 态能量较低，如 Ce 3+ 和其他的三价稀土离子不同，它带有一个 5d 1 电子，发光来自 5d-4f 的跃迁。
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