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这篇关于非均相催化剂失活和再生的综述按类型(化学、热和机械)和机制(中毒、结垢、热降解、蒸汽形成、汽-固和固-固反应以及磨损/破碎)对失活进行了分类。 参考这些领域的最新文献报告,详细审查了每种停用类型的主要特征和注意事项。 关于用于钴费托和选择性催化还原的催化剂失活机制的两个案例研究被认为为烧结、焦化、中毒和结垢等主题提供了额外的深度。 Deactivation of heterogeneous catalysts is a ubiquitous problem that causes loss of catalytic rate with time.
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