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In the season 4 episode "Pariah," Clark's girlfriend Alicia (Sarah Carter) became determined to leak his secret to the world, so she tricked Clark into using his powers in front of Chloe Sullivan (Allison Mack).
"Truth" is the eighteenth episode in the third season of Smallville, and sixty-second overall. It aired on April 21, 2004. When Chloe accidentally inhales a mysterious truth gas, she discovers it acts as a truth serum to anyone who comes in contact with her and decides to take advantage of her...
Saving Chloe, it's here that Clark finally reveals his secret. But while Chloe knew that her best friend had superpowers, she didn't know how different Clark Kent actually was from other...
Chloe Sullivan, the fiercely loyal and intellectually curious journalist, stumbled upon Clark Kent’s Kryptonian secret in the episode “Exodus,” the Season Two finale of Smallville.
In the episode “Pariah,” Clark’s girlfriend Alicia Baker reveals his secret to Chloe, hoping that Chloe will help Clark embrace his powers and identity. During a confrontation at the Talon, Chloe witnesses firsthand Clark’s extraordinary abilities and confronts him about his superpowers.
Smallville Season 3 Episode 18: Truth Summary: When Chloe accidentally inhales a mysterious krypto-gas, she discovers it acts as a truth serum to anyone who comes in contact with her and decides to take advantage of her new power by going to the Kents to find out Clark's secret.
Infamous: Directed by Glen Winter. With Tom Welling, Allison Mack, Erica Durance, Aaron Ashmore. Linda Lake comes back to Smallville and blackmails Clark to expose his true identity. However, Clark decides he will reveal his secret by himself. A fanatic teenager fakes a fall so Clark can save her.
"Shut Up" Kiss: In order to keep himself from spilling Clark's secret, Pete kisses Chloe instead and confesses to her that he's been in love with her since day one.
Clark apologized for not having called her and say that he was too busy, but Chloe tells him that she understood that he needed to continue with his life and that she was happy to have belonged to a part of his history.
In comics, whenever a hero lets people in an his/her secret, it always ends up putting the hero's loved ones in jeopardy. If Clark let all of his loved ones know his secret, and a bad guy found out who the Blur loved, then bad guy could use the loved one as bait against the Blur.