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My suspicion is that the info in the book relies on single-crystal x-ray diffraction experiment (1), where geometry of selenium oxydichloride cannot be determined solely from MO principles. So, here is the structure of dioxane-seleninyl-dichloride: As far as you can see, Se1 atom has three more neighbors: O1 from another [SeOClX2] [S e O C l X 2] unit, and O2 + O3 from dioxanes. The bond ...
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