为什么五氯化磷的杂化类型是 sp3？ - 知乎
27 June 2025 admin
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这里说的超价成键，是指形成超过四配位，也就是价电子数超过8个的化合物，例如磷可生成PCl5、硫可生成SF6，这种五配位以上的化合物显然不是用简单的sp3杂化轨道能解释的，因为sp3杂化轨道最多生成四配位以下的化合物。至于SO3之类的六价化合物实际只有三配位，用s轨道与p轨道形成杂化轨道的 ...
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